Polyphenylene Ether Macromonomer. Viii. Low Z-Axis Cte,Low Df Epoxy Laminates
Properties of printed circuit board laminates are a function of the type and levels of its components. Endeavors to a balance various performance criteria involve balancing the types and amounts of materials that can have similar or opposite effects on key properties. This paper explores the combined use of silica with use of silica and PPE macromonomer in optimizing properties of epoxy-based laminates. Silica exhibits low dielectric properties. However,particulate fillers can lower the toughness of composites. PPE macromonomer has been shown to be very effective in enhancing properties of epoxy resins. In particular,PPE macromer increased the toughness and improved the dielectric properties of epoxy-based laminates. Hence,the combination of PPE macromer and silica filler suggests a way to expand the performance window of epoxy-based laminates. Structure property evaluations were used to quantify the effects epoxy/silica,epoxy/PPE,and epoxy/PPE/silica on dielectric properties,CTE,toughness,and flexural properties. Types of silicas evaluated included ground,fused,platy,and diatomaceous earth. The results showed that using the macromoners in conjunction with silica give performance enhancements over epoxy-silica,or epoxy-PPE alone. Epoxy-based laminates were made which exhibited low Z-axis CTE and low loss tangent.