Soldering and Plating for Tin-Lead and Lead-Free Connection Reliability
Aerospace Defense High Performance (ADHP) electronics products primarily use tin-lead solders,but electrical and electronic component finishes (i.e.,platings) increasingly are designed for lead-free solders. The knowledge-gap on tin-lead integrity with new component finishes is growing over time. Also,the reworking of components to make them tin-lead compatible presents a component reliability risk. Therefore,it is important to understand and overcome the interfacial reliability risk for every combination of solder alloy and component finish used in ADHP products. The intermetallic compounds,which nucleate and grow during the soldering and use environments of electronics hardware,are of two general types. These are,1) Precipitation Compounds and 2) Diffusion Compounds. The precipitation compounds occur during the soldering process. The diffusion compounds can begin during the soldering process,and can grow during the environmental exposure of the solder connection to the product application (time at temperature,temperature cycling). We report numerous material combinations of soldering alloys and plating metals,where a common finding is that the growth of the diffusion compounds,at the solder-to-plating interface,is a precursor indicator of solder connection interfacial failure. The precursor is associated with vacancy accumulation and observation of Kirkendall voiding. Diffusion between the plating and the precipitation compounds leads to connection separation because the vacancy content of the plating can be up to twenty percent,and that vacancy content accumulates into area voids as the diffusion compounds grow. The diffusion compounds occur concurrent with,or subsequent to,the precipitation compounds. So the precipitation compounds are called first compounds. The diffusion compounds are called second compounds. The second (diffusion) compounds are stoichiometrically richer in the plating metal than are the first (precipitation) compounds. Technical examples show cross-sectional microstructures,and compound chemistry identifications,from the following solder-to-plating systems: tin-lead-to-gold,tin-lead-to-copper,indium-lead-to-gold,gold-germanium-to-nickel,tin-lead-to-iron-nickel and tin-lead-to-palladium. The influence of the first compounds on the mechanical properties of the solder connection can be characterized with predictability equations. However,the second compounds need to be avoided or minimized,by means of material selection (solder alloy,volume),plating design (metal,thickness,area) and processing parameters (plating,soldering). Lead-free solder connections to copper and iron-nickel finishes indicate qualification testing is needed,for lead-free solder alloys,showing their failure precursor compounds and voids are minimized.